Bioinspired NiFe-gallate metal-organic frameworks for highly efficient oxygen evolution electrocatalysis

We report the synthesis of a bioinspired NiFe-gallate metal-organic framework on carbon paper using gallic acid (GA) as the organic ligand, nickel chloride hexahydrate and iron(ii) chloride tetrahydrate as metal sources by a one-step hydrothermal method. The as-prepared NiFe-GA on carbon paper exhibits excellent oxygen evolution reaction (OER) performance, which requires overpotentials of 185 mV and 236 mV to achieve 10 mA cm(-2) and 100 mA cm(-2) in 1.0 M KOH, respectively. In situ electrochemical and density functional theory calculation results reveal that the presence of Fe and GA favors the generation of active oxygen species and the catalytic active Ni- and Fe-sites facilitate the charge transport to adsorbed OHad reducing the activation barrier of OHad deprotonation to form O-ad intermediates, thereby contributing the superior OER performance.