Discoloration of methylene blue at neutral pH by heterogeneous photo-Fenton-like reactions using crystalline and amorphous iron oxides

Different iron oxides were evaluated for the discoloration of methylene blue (MB) at neutral pH by heterogeneous photo-Fenton-like reactions with a UV-LED lamp. Fe3O4, alpha-Fe2O3, and a-FeOOH catalysts were synthesized and characterized by X-ray diffraction, scanning electron microscopy (SEM), Raman spectroscopy, Fourier transform infrared spectroscopy, and adsorption isotherms of N-2. The results show high crystallinity and relatively low surface areas for Fe3O4 and alpha-Fe2O3, and amorphous structure with high surface area for the case of a-FeOOH. The discoloration of MB by iron oxides as catalysts was studied using UV-Vis spectroscopy. Despite the relative high adsorption of MB for magnetite (12%) compared to the other oxides, it shows a slow discoloration kinetics. Besides, amorphous oxide (named a-FeOOH) shows a higher discoloration kinetics with negligible adsorption capacity. The pseudo first-order kinetic constant values for Fe3O4, alpha-Fe2O3, and a-FeOOH are 5.31 x 10(-3), 6.89 x 10(-3), and 13.01 x 10(-3) min(-1); and the discoloration efficiencies at 120 min were 56, 60, and 82%, respectively. It was testified that low crystallinity iron oxide can be used in the efficient discoloration of MB by photo-Fenton process with a hand UV-A lamp.