A ruthenium nanocatalyst for the atmospheric hydrogenation of 1,5-cyclooctadiene
JOURNAL OF CHEMICAL RESEARCH(2022)
摘要
A ruthenium nanocatalyst is utilized for the first time for the highly efficient and selective hydrogenation of 1,5-cyclooctadiene under atmospheric hydrogen pressure. Under the optimized reaction conditions, the conversion of 1,5-cyclooctadiene and the selectivity for cyclooctene are >99% and 95%, respectively. The turnover frequency is 451 h(-1), which is higher than that ever reported for Ru complex catalysts.
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关键词
atmospheric hydrogen pressure,1,5-COD,Ru nanocatalyst,selective hydrogenation,thermoregulated phase-transfer catalysis
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