Comment on "Linear and bent triatomic molecules are not qualitatively different!"

CANADIAN JOURNAL OF PHYSICS(2021)

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摘要
Jensen (Can. J. Phys. 98, 506 (2020). doi: 10.1139/cjp-2019-0395) presents theoretical justification for the claim that linear triatomic molecules are necessarily observed to be bent. The basis of the assertion is that the expectation value of the supplement of the bending angle, (rho) over bar used in Jensen's paper, is calculated to be positive. In this comment, we examine the interpretation of the expectation values of (rho) over bar in stationary states, and indicate that Jensen's claim contradicts a basic principle of quantum mechanics that the energy and geometrical variables cannot have definite values at the same time.
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关键词
linear molecule, bending angle, expectation value, permanent dipole moment, vibration rotation spectra
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