Enhanced phosphorescence of Pd(II) and Pt(II) complexes adsorbed onto Laponite for optical sensing of triplet molecular dioxygen in water

Two isoleptic complexes involving Pd(II) and Pt(II) centres with a tetradentate luminophoric ligand were adsorbed onto Laponite (LAP), yielding H2O-dispersible nanohybrids with remarkable photoexcited state properties. The adsorption promoted rigidification of the coordination compounds and suppression of roto-vibrational deactivation pathways, thus enhancing the performance of the molecular species. Interestingly, room temperature phosphorescence was achieved in the case of the Pd(II)containing nanohybrid along with a marked O-3(2) sensitivity, whereas the photoluminescence of the Pt(II)-based material showed only a mild dependence on the presence of O-3(2) while reaching up to 37% quantum yield.