Cyclopentadienyl lanthanide borohydrides derived from the unsubstituted cyclopentadienyl ligand. Unprecedented structural diversity and ε-caprolactone polymerization
Inorganica Chimica Acta（2022）
Abstract
•The systematic study of the series of cyclopentadienyl borohydride Ln3+ complexes.•Five different structural types of cyclopentadienyl Neodymium borohydride complexes.•Different complex cyclopentadienylborohydride lanthanide anions.•Neodymium cyclopentadienylborohydrides initiate ε-caprolactone polymerization.
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Key words
Lanthanide complexes,Cyclopentadienyl,Tetrahydroborates,Crystal structure
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