Styrene selective oxidation to benzaldehyde catalyzed by acylhydrazone Mo complexes: Reaction parameter effects and kinetics

Shuang Yang,Gong Li, Yujie Yang,Mengdi Zhu,Yuejiao Fu,Na Xing,Lei Shi

Inorganica Chimica Acta（2022）

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摘要

•Three novel acylhydrazone molybdenum complexes were synthesized.•Their catalytic activities in styrene oxidation were studied and oxidoperoxido molybdenum species were found to be the intermediates.•Kinetics of the reaction over the catalysts were studied.

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关键词

Styrene catalytic oxidation,Molybdenum complex,Crystal structure,Homogeneous catalysis,Kinetic calculation

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