Degradation of Reactive Brilliant Red X-3B by Photo-Fenton-like Process: Effects of Water Chemistry Factors and Degradation Mechanism

Azo dye wastewater belongs to the highly concentrated organic wastewater, which is difficult to be treated by traditional biological processes. The oxidation efficiency of a single physicochemical method is not considerable. Recent research indicated that the advanced oxidation processes (AOPs) based on the highly reactive hydroxyl radical (center dot OH) became one of the preferred methods in dealing with such dye wastewater. In this paper, the typical azo dye, reactive brilliant red X-3B, was employed as the target pollutant, and the transition metal Mn and hydrogen peroxide as the catalysts. A photo-Fenton-like process, UV/Mn2+-H2O2 system, was established, which enables a combination of various technologies to improve azo dye degradation efficiency while reducing disposal costs. The results indicated that the UV/Mn2+-H2O2 system had the synergism of Mn2+/H2O2 and UV/H2O2, which was 2.6 times greater than the sum of the two individual effects. And the degradation of X-3B reached the optimum under the conditions of 0.59 mmol/L of the Mn2+, 10 mmol/L of the H2O2, pH = 6 and a high level of DO. The center dot OH, generated from chem-catalytic and photocatalytic decomposition of H2O2, played the predominant role in the decolorization of X-3B and mineralization of its intermediates. The center dot OH tended to attack and break the chromophore group, resulting in the rapid decolorization of X-3B. The azo bond in X-3B was easy to be decomposed in the form of N-2, while the triazinyl group was recalcitrant for ring opening. The degradation process of the UV/Mn2+-H2O2 system preferred to be conducted at an acidic condition and appropriate concentrations of Mn2+ and H2O2. The alkaline condition would decrease the utilization of H2O2, and excessive H2O2 would also quench the center dot OH.