Study on the CO-SCR anti-sulfur and denitration performance of V-doped OMS-2 catalysts

A catalyst with high NO conversion rate and good sulfur resistance is the key to CO-SCR. Herein, the V-doped OMS-2 molecular sieves were successfully synthesized through the hydrothermal method. The resulting catalyst was characterized by X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscope(TEM) and specific surface area analyzer (BET). The results showed that the addition of V increased the average grain size of OMS-2 and the concentration of oxygen va-cancies. Meanwhile, V replaced the K site in OMS-2 and participated in the oxidation-reduction reaction together with Mn. Compared with the V-0-OMS-2, the NO conversion rate of V0.2 -OMS-2 in a sulfur-free environment increased from 60% to 81% at 150 degrees C and 75%-94% at 300 degrees C. The NO conversion rate could still maintain as 80% at 300 degrees C in a sulfur-containing environment.