Acylative kinetic resolution of 1,1 '-binaphthyl-8,8 '-diamines by organocatalysis
TETRAHEDRON(2022)
摘要
A method for kinetic resolution of 2,2'-disubstituted 1,1'-binaphthyl-8,8'-diamines has been developed by enantioselective acylation of the amino group with chiral pyrrolidinopyridine organocatalysts. Multiple hydrogen-bonding interactions as well as pi-pi interaction between the catalyst and the diamines were proposed to be responsible for the accelerative enantioselective acylation. (C) 2021 Elsevier Ltd. All rights reserved.
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关键词
Kinetic resolution, Amine, Acylation, Organocatalysis, Hydrogen bond
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