Cationic half-sandwich ruthenium (II) complexes ligated by pyridyl-triazole ligands: Transfer hydrogenation and mechanistic studies

Polyhedron（2022）

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摘要

Novel cationic ruthenium half-sandwich complexes of 1-substituted-4-pyridyl-1H-1,2,3-triazole were found to be efficient catalyst precursors for transfer hydrogenation reactions. Based on several experimental observations, a plausible mechanism for the process is proposed.

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关键词

Cationic ruthenium half-sandwich complexes,Ruthenium arene complexes,Transfer hydrogenation,Mechanistic investigation

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