Synthesis and Characterization of Anatase TiO2 Nanorods: Insights from Nanorods' Formation and Self-Assembly

Highly crystalline, organic-solvent-dispersible titanium dioxide (TiO2) nanorods (NRs) present promising chemicophysical properties in many diverse applications. In this paper, based on a modified procedure from literature, TiO2 NRs were synthesized via a ligand-assisted nonhydrolytic sol-gel route using oleic acid as the solvent, reagent, and ligand and titanium (IV) isopropoxide as the titanium precursor. This procedure produced monodisperse TiO2 NRs, as well as some semi-spherical titania nanocrystals (NCs) that could be removed by size-selective precipitation. X-ray diffraction and selected area electron diffraction results showed that the nanorods were anatase, while the semipheres also contained the TiO2(B) phase. By taking samples during the particle growth, it was found that the average length of the initially grown NRs decreased during the synthesis. Possible reasons for this unusual growth path, partially based on high-resolution transmission electron microscopy (HRTEM) observations during the growth, were discussed. The dispersion of anatase TiO2 nanorods was capable of spontaneous formation of lyotropic liquid crystals on the TEM grid and in bulk. Considering high colloidal stability together with the large optical birefringence displayed by these high refractive index liquid crystalline domains, we believe these TiO2 NRs dispersions are promising candidates for application in transparent and switchable optics.