Bisphosphorylation of anhydrides – convenient access to bisphosphonates with a P–O–C–P motif
Chemical Communications(2022)
摘要
A novel strategy of bisphosphorylation of anhydrides with P(O)–H reagents via a DMAP-catalyzed and DBU-promoted process has been developed. These one-step transformations proceed efficiently to provide convenient access to a variety of P–O–C–P motif containing organophosphorus compounds. In addition, the gram-scale synthesis and the efficient recovery of the by-product highlight the sustainability and applicability of this method.
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关键词
bisphosphonates,anhydrides,p-o-c-p
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