Material Regulation Engineering Towards xLiFePO ₄·yLi ₃V ₂(PO ₄) ₃ Composites in Application-Oriented

The development of LiFePO4 (LFP) in high-power energy storage devices is hampered by its slow Li-ion diffusion kinetics. Constructing the composite electrode materials with vanadium substitution is a scientific endeavor to boost LFP’s power capacity. Herein, a series of xLiFePO4·yLi3V2(PO4)3 (xLFP·yLVP) composites are fabricated by a simple spray-drying approach. We propose that 5LFP·LVP is the optimal choice for Li-ion battery promotion, owning to its excellent Li-ion storage capacity (material energy density of 413.6 W h kg −1), strong machining capability (compacted density of 1.82 g cm−3) and lower raw material cost consumption. Furthermore, 5LFP·LVP || LTO Li-ion pouch cell also presents a prominent energy storage capability. After 300 cycles of a constant current test at 400 mA, 75% of the initial capacity (379.1 mA h) is achieved, with around 100% of Coulomb Efficiency. The capacity retention of 60.3% is displayed for the 300th cycles when discharging at 1200 mA, with the capacity fading per cycle 0.15%. This prototype provides a valid and scientific attempt to accelerate the development of xLFP·yLVP composite in application-oriented Li-ion batteries.