Synthesis of β‐Keto Sulfoxides via Copper(II)‐Catalyzed Aerobic Oxidation

Guowei Xiong,Liangfeng Huang, Zhang Gong, Can Wang,Yunfeng Chen

Advanced Synthesis and Catalysis（2022）

引用 2|浏览0

暂无评分

摘要

A copper‐catalyzed cross‐dehydrogenative coupling (CDC) reaction between aromatic aldehydes and DMSO was developed, which afforded β‐keto sulfoxides in 73–92% yields. The reaction process involved base‐promoted DMSO addition to aldehydes, and copper‐catalyzed aerobic oxidation. Furthermore, the aromatic alcohols which could be oxidized to aldehydes are also suitable substrates for this catalytic system.

查看译文

关键词

copper-catalyzed,CDC reaction,aerobic oxidation,β-keto sulfoxides

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要