Physical properties and electronic structure of single-crystal KCo2As2

We present a method for producing high quality $\mathrm{K}{\mathrm{Co}}_{2}{\mathrm{As}}_{2}$ crystals, stable in air and suitable for a variety of measurements. X-ray diffraction, magnetic susceptibility, electrical transport, and heat capacity measurements confirm the high quality and an absence of long range magnetic order down to at least 2 K. Residual resistivity values approaching 0.25 $\ensuremath{\mu}\mathrm{\ensuremath{\Omega}}$ cm are representative of the high quality and low impurity scattering, and a Sommerfeld coefficient $\ensuremath{\gamma}=7.3 \mathrm{mJ}/\mathrm{mol}$ ${\mathrm{K}}^{2}$ signifies weaker correlations than the Fe-based counterparts. Together with Hall effect measurements, angle-resolved photoemission experiments reveal a Fermi surface consisting of electron pockets at the center and corner of the Brillouin zone, in line with theoretical predictions and in contrast to the mixed carrier types of other pnictides with the $\mathrm{Th}{\mathrm{Cr}}_{2}{\mathrm{Si}}_{2}$ structure. A large, linear magnetoresistance of 200% at 14 T, together with an observed linear and hyperbolic, rather than parabolic, band dispersions are unusual characteristics of this compound.