Supplementary material to "Measurement report: Characterization and source apportionment of coarse particulate matter in Hong Kong: Insights into the constituents of unidentified mass and source origins in a coastal city in southern China"

Coarse particulate matter (i.e. PM with an aerodynamic diameter between 2.5 and 10 mu m - PM2.5 and PM10 - or PMcoarse) has been increasingly recognized for its importance in PM10 regulation because of its growing proportion in PM10 and the accumulative evidence for its adverse health impact. In this work, we present comprehensive PMcoarse speciation results obtained through a 1-year-long (January 2020-February 2021) joint PM10 and PM2.5 chemical speciation study in Hong Kong, a coastal and highly urbanized city in southern China. The annual average concentration of PMcoarse is 14.9 +/- 8.6 mu g m(-3) (+/- standard deviation), accounting for 45 % of PM10 (32.9 +/- 18.5 mu g m(-3)). The measured chemical components explain similar to 75 % of the PMcoarse mass. The unexplained part is contributed by unmeasured geological components and residue liquid water content, supported through analyses by positive matrix factorization (PMF) and the thermodynamic equilibrium model ISORROPIA II. The PMcoarse mass is apportioned to four sources resolved by PMF, namely soil dust/industrial and coal combustion, construction dust/copper-rich emissions, fresh sea salt, and an aged sea salt factor containing secondary inorganic aerosols (mostly nitrate). The PMcoarse concentration and source composition exhibit a distinct seasonal variation, a result mainly driven by the source areas the air masses have travelled through as revealed by back-trajectory analysis. In summer when the site is dominated by marine air mass, PMcoarse is the lowest (average= 8.1 mu g m(-3)) and sea salt the largest contributor (47 %), followed by the two dust factors (36 % in total). In winter when the site receives air mass mainly from the northern continental region, PMcoarse concentration triples (24.8 mu g m(-3)), with the two dust factors contributing three quarters of the aerosol mass. The potential dust source areas are mapped using the concentration-weighted trajectory technique, showing either the Greater Bay Area or the greater part of southern China as the origin of fugitive dust emissions leading to elevated ambient PMcoarse loadings in Hong Kong. This study, the first of this kind in our region, provides highly relevant guidance for other locations with similar monitoring needs. Additionally, the study findings point to the need for further research on the sources, transport, aerosol processes, and health effects of PMcoarse.