Exploiting the tuneable density of scCO2 to improve particle size control for dispersion polymerisations in the presence of poly(dimethyl siloxane) stabilisers

European Polymer Journal(2022)

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摘要
•Dispersion polymerisations at varying scCO2 pressure show particle size change.•Solubility of PDMS-MA stabiliser in scCO2 affects particle size.•Particle size control achieved without the use of cosolvents.•Pressure limits of dispersion polymerisation in scCO2 explored.•Attainable PMMA particle size range expanded to 0.26–7.14 μm.
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关键词
Supercritical CO2,Solubility,Dispersion polymerisation,Particle size control,Green solvent
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