Revealing the peculiar local behavior of manganese and cobalt in diffusion-doped сalcium orthovanadate Ca₃(VO₄)₂

Galina M Kuz'micheva,Liudmila I. Ivleva,Irina A. Kaurova,Evgeny V. Khramov,Vladimir A. Lazarenko,Victor B. Rybakov,Roman D Svetogorov,Maxim E Doroshenko

Dalton Transactions（2022）

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摘要

Laser Ca 3 (VO 4 ) 2 single crystals (СVO; space group R 3 c , Z = 21) with crystallochemical formula Ca1 18 Ca2 18 Ca3 18 Ca4 6 (Ca5 + Са5 А ) 3 (V1 18 V2 18 V3 6 )O 168 grown by the Czochralski method were doped with Мn 2 O 3 (CVO:Мn 2 O 3 ) and Сo 3 O 4 (CVO:Co 3 O 4 )...

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Revealing the peculiar local behavior of manganese and cobalt in diffusion-doped сalcium orthovanadate Ca3(VO4)2

Revealing the peculiar local behavior of manganese and cobalt in diffusion-doped сalcium orthovanadate Ca₃(VO₄)₂