Low-temperature heat capacity and thermodynamic functions of thulium and lutetium titanates and Schottky anomaly in Tm2Ti2O7
The Journal of Chemical Thermodynamics（2022）
Abstract
•Thulium and lutetium titanates were synthesized from oxides by solid state reaction.•Structural refinement and measurements by adiabatic calorimetry were carried out.•Anomal Schottky contribution in Tm2Ti2O7 and thermodynamic functions were determined.
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Key words
Rare earth titanates,Adiabatic calorimetry,X-ray diffraction,Heat capacity,Schottky anomaly,Thermodynamic properties
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