Kinetics of Aqueous Persulfate-Induced Oxidative Degradation of Heptafluorobutanoate, Pentafluoropropionate, and Trifluoroacetate

Alexander A. Marchione,Elizabeth L. Diaz, Jill E. Boyle

Journal of Fluorine Chemistry（2021）

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摘要

•Kinetics of reaction of small perfluorocarboxylates with persulfate are presented•Perfluorobutanoate and propionate are faster to react than trifluoroacetate•Recombination to perfluoroalkanes observed at higher concentrations

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关键词

Perfluorocarboxylates,Degradation,Persulfate,Kinetics,Nuclear magnetic resonance spectroscopy,Raman spectroscopy

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