Synthesis of bis(trifluoromethyl)alkylated trisubstituted alkenes via highly regioselective catalyzed hydrosilylation reaction of hexafluoro-2-butyne and their reactivity

Nataliia V. Kirij,Andrey A. Filatov,Yurii L. Yagupolskii,Sheng Peng,Andrew Jackson

Journal of Fluorine Chemistry（2022）

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摘要

•Hydrosilylation reaction of hexafluoro-2-butyne (HFB) with various silanes.•The stereochemistry of the hydrosilylation products.•New secondary and tertiary silylated ethers bearing trifluoromethyl groups were synthesized.

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关键词

Hydrosilylation,Hexafluoro-2-butyne,Transition-metal-catalysis,Bis(trifluoromethyl)containing vinylsilanes

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