Cr-incorporated Uranium Nitride Composite Fuels with Enhanced Mechanical Performance and Oxidation Resistance

Cr-incorporated UN (Cr-UN) composite fuels with different Cr amounts up to 10 wt% are fabricated by spark plasma sintering, and their microstructure and phase heterogeneity are analyzed. Highly densified microstructure and homogeneous Cr distribution are identified for the Cr-incorporated UN pellets, demonstrating a liquid sintering characteristic with a Cr enriched phase on the UN grain boundaries. A ternary phase U2CrN3 forms in the Cr-UN matrix with Cr amounts of 5 wt% and 10 wt%. The SPS densified Cr-UN composite pellets display greatly-improved thermal conductivity and simultaneously high hardness and fracture toughness. The fracture toughness of the Cr-incorporated UN pellet is similar to 5.5 MPa-m(1/2), representing almost 130% enhancement as compared to that of monolithic UN sintered at the same condition. The Cr-incorporated UN pellets also display enhanced oxidation resistance as evidenced by increased onset temperature for oxidation to 450 ? for the 5 wt% Cr-UN. These results highlight that Cr additive and the formation of a ternary phase can be useful to improve the thermal-mechanical properties and oxidation resistance of UN fuels with well-maintained high fissile element density. (c) 2021 Elsevier B.V. All rights reserved.