12-Tungstophosphoric acid-encapsulated metal-organic framework UiO-66: A promising catalyst for the esterification of acetic acid with n-butanol
Journal of the Taiwan Institute of Chemical Engineers(2022)
Abstract
•HPW@UiO-66 was successfully synthesized by a one-pot hydrothermal method.•HPW was incorporated into the UiO-66 structure with a uniform distribution.•The highest conversion of acetic acid (80.2%) was achieved over 30HPW@UiO-66.•HPW@UiO-66 showed high structure stability and reusability.•An Eley-Rideal model mechanism for the esterification reaction was proposed.
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Key words
Phosphotungstic acids,UiO-66,Metal-organic frameworks,Catalyst,Esterification
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