12-Tungstophosphoric acid-encapsulated metal-organic framework UiO-66: A promising catalyst for the esterification of acetic acid with n-butanol

Tianlin Ma,Daojun Liu, Zheng Liu,Jinfeng Xu,Yao Dong,Gangling Chen,Zhi Yun

Journal of the Taiwan Institute of Chemical Engineers（2022）

Cited 12|Views6

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Abstract

•HPW@UiO-66 was successfully synthesized by a one-pot hydrothermal method.•HPW was incorporated into the UiO-66 structure with a uniform distribution.•The highest conversion of acetic acid (80.2%) was achieved over 30HPW@UiO-66.•HPW@UiO-66 showed high structure stability and reusability.•An Eley-Rideal model mechanism for the esterification reaction was proposed.

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Key words

Phosphotungstic acids,UiO-66,Metal-organic frameworks,Catalyst,Esterification

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