C- and S‑Shaped Perylene Diimide Heterohelicenes: Modular Synthesis and Spiral-Stair-Like π‑Stacking
Organic Letters(2022)
摘要
A number of C- and S-shaped perylene diimide (PDI) heterohelicenes with high dipole moments were synthesized from simple perylene tetrabutylester (PTE). Taking advantage of the weak coordination ability of the sterically crowded peri ester groups in PTE, efficient Rh(III)-catalyzed 2,8- and 2,11-bisiodinations of the perylene core were realized. The 2,8- and 2,11-diiodinated PTEs and PDIs represent key synthons for further ortho-π-extensions. In contrast to most helical π-skeletons that feature loose molecular packings, enantiomerically pure C-shaped PDI azahelicenes adopt unique spiral-stair-like π-stacking superstructures.
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关键词
perylene diimide heterohelicenes,modular synthesis,spiral-stair-like
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