Kinetic study of trichloroethylene combustion on exchanged zeolites catalysts

JOURNAL OF HAZARDOUS MATERIALS(2011)

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摘要
In this paper is presented a kinetic study of the catalytic combustion of trichloroethylene (TCE) over Y-zeolites exchanged with several cations. The catalysts, based on zeolite, were prepared by ion exchange and characterized by means of physico-chemical techniques and then tested under kinetic conditions. The kinetic results obtained were interpreted using kinetic models of power-law type and Eley-Rideal. The results obtained indicate that catalyst Y-Cr is more active than Y-Co catalyst. The greater activity of catalyst exchanged with Cr can be attributed to the higher acidity that presented these catalysts. (C) 2011 Elsevier B.V. All rights reserved.
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关键词
Oxidation,Trichloroethylene,Exchanged zeolites,Kinetic data
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