Preparation of Hollow Niobium Oxide Nanospheres with Enhanced Catalytic Activity for Oxidative Desulfurization

Hollow niobium oxide nanospheres were successfully synthesized by using prepared three-dimensional (3D) mesoporous carbon as the hard template. The 3D mesoporous carbon materials were prepared by using histidine as the carbon source and silica microspheres as the hard template. The samples were characterized by XRD, BET, SEM, TEM and other methods. The results show that the prepared niobium oxide nanospheres have a hollow spherical structure with an outer diameter of about 45 nm and possess a high specific surface area of 134.3 m(2)center dot g(-1). Furthermore, the 3D mesoporous carbon materials have a typical porous structure with a high specific surface area of 893 m(2)center dot g(-1). The hollow niobium oxide nanospheres exhibit high catalytic activity in oxidative desulfurization. Under optimal reaction conditions, the DBT conversion rate of the simulated oil is as high as 98.5%. Finally, a possible reaction mechanism is proposed.