Promising seawater hydrothermal combining electro-assisted pretreatment for corn stover valorization within a biorefinery concept

In this study, for the first time, seawater hydrothermal (SH) pretreatment combining subsequent electro-generated alkaline hydrogen peroxide (EAHP) pretreatment was proposed to achieve an effective fractionation of corn stover into high value-added products. During SH pretreatment, complex ions in natural seawater (Mg2+, Ca2+ and Cl-) were used to promote depolymerization of xylan into xylo-oligosaccharides with 49.37% yield (190 C,40 min), 18.52% higher than that of deionized water. Subsequent EAHP treatment not only provided a green and economical way to produce hydrogen peroxide but also synchronously realized satisfied delignification (94.91%). The integrated pretreatment resulted in 91.16% of glucose yield, which was about 5.6 times more than that of unpretreated corn stover. In addition, the recovered lignin fraction which has a potential application in functional materials were investigated by FTIR, 2D-HSQC NMR and GPC. In short, this work provided a novel and environmentally-friendly strategy for biorefinery-based fractionation of corn stover.