Interactions of Si⁺(²P_J) and Ge⁺ (²P_J) with rare gas atoms (He–Rn): interaction potentials, spectroscopy, and ion transport coefficients

Alexander R. Davies,Aiden Cranney,Larry A. Viehland,Timothy G. Wright

Physical Chemistry Chemical Physics（2022）

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摘要

RCCSD(T) potentials for Si+ and Ge+ interacting with RG atoms (RG = He–Rn) are presented, including extrapolating to the basis set limit and spin–orbit coupling. These potentials are used to derive spectroscopic and ion transport parameters.

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rare gas atoms,interactions potentials,interactions transport coefficients,spectroscopy

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Interactions of Si+(2PJ) and Ge+ (2PJ) with rare gas atoms (He–Rn): interaction potentials, spectroscopy, and ion transport coefficients

Interactions of Si⁺(²P_J) and Ge⁺ (²P_J) with rare gas atoms (He–Rn): interaction potentials, spectroscopy, and ion transport coefficients