Heterostructure‐Regulated Metal Silicates Composite Material for Enhancing the Lithium‐Ion Batteries Performance
ChemElectroChem(2022)
摘要
Noticeable surface reaction in the energy storage mechanism has attracted tremendous research due to its relationship with electrochemical capacity and rate capability. In this work, in-situ grown heterostructured metal silicates are prepared through a facile hydrothermal method. The composites are employed as anodes for supercapacitor and lithium-ion batteries (LIBs). The ratio of cobalt and copper in the heterostructure has a significant effect on its properties, including porosity, electrical conductivity, and pseudo-capacitance contribution during the energy storage process. The combination of metal silicates, heterostructure, and porous bio-mass derived carbon into one system results in a unique electrode material with optimized reaction kinetics. The integration leads to a superior capacity and rate capability. Specifically, the cobalt silicate/copper silicate heterostructure composites present improved electrochemical performance as anode for LIBs and supercapacitor. For lithium-ion storage, the B-C@CoCuSi-(3-1) delivers a capacity of 574.5 mAh g(-1). When used as an anode material for supercapacitor, the B-C@CoCuSi-(1-3) shows a capacitance of 80.4 F g(-1).
更多查看译文
关键词
metal silicates, heterostructure, lithium-ion battery, supercapacitor, electrochemical performance
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要