1,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (Ag^I) and heterometallic (Ag^I/U^VI) coordination polymers

Ganna A. Senchyk,Andrey B. Lysenko,Harald Krautscheid, Eduard B. Rusanov,Miroslaw Karbowiak,Kostiantyn V. Domasevitch

CrystEngComm（2022）

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摘要

A 1,2,4-triazol-4-yl-acetic acid (trGly-H) was used for the synthesis of AgI and AgI/UVI coordination polymers. The composition space diagram was built for the AgNO3/trGly-H/UO2(NO3)2·6H2O system shows the crystallization fields of two AgI/UVI-compounds were found.

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ditopic ligand,polymers,coordination

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1,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (AgI) and heterometallic (AgI/UVI) coordination polymers

1,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (Ag^I) and heterometallic (Ag^I/U^VI) coordination polymers