The use of gluconic acid as an additive in magnetic paper

As magnetic fillers, e.g., nanomagnetite, reduce the mechanical strength of produced magnetic papers, additives should be used. In this study, nanomagnetic papers were produced through an in-situ method by synthesizing magnetic cellulose fibers with kraft fibers and iron salts in a nitrogen atmosphere. Then, gluconic acid was added to improve the mechanical strength. The properties of nanomagnetic papers were investigated via different methods. The nanomagnetite particle size ranged from 1 to 84 nm. Scanning electron microscopy demonstrated the deposited nanomagnetite particles on the surface of the fibers. The saturation magnetization of the nanomagnetic papers treated with 0%, 1%, 2%, or 3% gluconic acid (per dry weight of the pulp) was 7.54, 5.64, 4.81, and 0.55 emu/g, respectively. The nanomagnetite particles loaded on the fibers decreased as the gluconic acid content was increased. The nanomagnetic papers exhibited superparamagnetic behavior. Elevation of the gluconic acid content caused an increased tensile and burst index, as well as a reduced tear index. It also led to augmented brightness and diminished opacity.