Identification of Fe(iii)–OH species as a catalytic intermediate in plant peroxidases at high H2O2 concentration

New Journal of Chemistry(2022)

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Abstract
The structure for compound III formed after exposure of plant heme peroxidases to excess H2O2 seems to be a hydroxylated form, providing new evidence for understanding the structural basis of the substrate-induced suicidal behavior of these enzymes.
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