A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal pi-Planes by a One-Pot Reaction
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(2022)
Abstract
Triptycenes with their predefined D-3h-symmetry are excellent molecular building blocks to construct shape-persistent nanobelts having pi-orbitals orthogonal to the ring plane. However, up to now, there are only a very few examples of fused and rigid iptycene nanobelts synthesized in several consecutive steps in overall yields below 1 %. Here we present the simple one-step one-pot approach to an iptycene nanobelt, which forms in >2 % and can readily be isolated from the polymeric by-product by gel-permeation chromatography.
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Key words
Cycloiptycene,N-Heterocyclic aromatic compounds,Nanobelts,Phenazine,Triptycene
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