A two-electron transfer mechanism of the Zn-doped δ-MnO₂ cathode toward aqueous Zn-ion batteries with ultrahigh capacity

Wen Zhao,Jared Fee,Harshul Khanna,Seth March,Nathaniel Nisly,Samantha Joy B. Rubio,Can Cui,Zhuo Li,Steven L. Suib

Journal of Materials Chemistry A（2022）

引用 15|浏览21

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摘要

We developed a Zn-doped δ-MnO2 material via a microwave-assisted method for the cathode in aqueous ZIBs. The successive insertion of H+ and Zn2+ and deep two-electron transfer routes mechanism is revealed systematically by ex situ experiments.

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A two-electron transfer mechanism of the Zn-doped δ-MnO2 cathode toward aqueous Zn-ion batteries with ultrahigh capacity

A two-electron transfer mechanism of the Zn-doped δ-MnO₂ cathode toward aqueous Zn-ion batteries with ultrahigh capacity