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Electrochemistry Enabled Nickel-Catalyzed Selective C-S Bond Coupling Reaction

Yang Wang,Feng Zhang,Yi Wang,Yi Pan

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY（2022）

Cited 5|Views4
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Abstract
This work describes an electrochemical enabled nickel-catalyzed chemoselective C-S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C-S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.
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Key words
Electrochemistry,Chemoselective thiolation,Sodium sulfinate,Nickel catalysis,Disproportionation
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