Hydrogen bonding distribution and its effect on sensitivity of planar tricyclic polyazole energetic materials

A series of planar tricyclic polyazole, energetic salts and energetic co-crystal were effectively synthesized via simple process from commercial materials. These structures of 5,5 & PRIME;-(2-nitro-1H-imidazole-4,5-diyl)bis(1H-tet-razole) (neutral compound 3), Ammonium 5,5 & PRIME;-(2-nitro-1H-imidazole-4,5-diyl)bis(1H-tetrazole) (4), Hydrox-ylammonium 5,5 & PRIME;-(2-nitro-1H-imidazole-4,5-diyl)bis(1H-tetrazole) (5) and Hydroxylamine . 2[5,5 & PRIME;-(2-nitro-1H-imidazole-4,5-diyl)bis(1H-tetrazole)] (co-crystal 7) which are combined with two neutral molecules 3 and one hyroxylamine were confirmed by X-ray diffraction analysis. Compared with the compounds 3 and 5, energetic co-crystal 7 exhibit better thermal stabilities with an increase of 31?degrees C or 62 degrees C, respectively. Additionally, compound 3 (IS: > 60 J; FS > 360 N), 4 (IS: > 60 J; FS > 360 N) and 5 (IS = 39 J; FS > 360 N) are nearly insensitive toward mechanical stimuli, but co-crystal 7 (IS < 1 J) possesses extremely high impact sensitivities. Crystal and Hirschfeld analyses have demonstrated that the difference of hydrogen bonding distribution lead to the extremely difference of sensitivity between neutral compound 3 and co-crystal 7, which will help to accel-erate the creating of new nitrogen-rich energetic materials for different applications.