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Synthese d'antibiotiques triterpeniques a partir d'acides biliaires : III. Syntheses par epoxydation et cyclopropanation d'intermediaires susceptibles de conduire aux derives methyles 14αδ(8,9)

Tetrahedron(1986)

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Abstract
Abstract Epoxidation and cyclopropanation of various derivatives of apocholic acid have been studied in order to obtain Intermediates which could lead to the structures indicated in the title. Stereochemistry and spectroscopic data of the obtained compounds are discussed on the basis of the diffraction crystal structures.
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