Rational Design of Mn-Salen Epoxidation Catalysts: Preliminary Results.

Naoki Hosoya,Akira Hatayama,Ryo Irie,Hidehiko Sasaki,Tsutomu Katsuki

ChemInform（1994）

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摘要

Abstract (Salen)manganese(III) complex 7 designed on the basis of the new proposal on the olefin's access to metal-oxo bond and complex 10 having axial chirality in salicylaldehyde part were found to be effective catalysts for the epoxidation of unfunctionalized olefins, especially for cis-olefins.

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