Asymmetric trimethylsilylcyanation of aldehydes catalyzed by chiral salen TiIV complexes with theC 1 symmetry
Russian Chemical Bulletin（1997）
Abstract
Asymmetric trimethylsilylcyanation of a number of aromatic and aliphatic aldehydes catalyzed by chiral TiIV complexes preparedin situ from Ti(OPri)4 and (1S)-[N,N′-bis(2′-hydroxy-3′-tert-butylbenzylidene)]-1,2-diaminoalkanes gives products with (S)-absolute configurations.
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Key words
chiral salen tiiv complexes,asymmetric trimethylsilylcyanation,aldehydes
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