Synthesis and reactivity of pentavalent biphenyl-2,2′-ylenebismuth derivatives
Journal of The Chemical Society-perkin Transactions 1(2000)
摘要
Phenylbiphenyl-2,2′-ylenebismuth diacetate reacted with nucleophiles under basic conditions to give modest to good yields of the C-phenylated substrates. Under copper catalysis, it reacted with hydroxy or amino groups to give the products of O- or N-phenylation. In both sets of reaction conditions, this reagent showed a reduced reactivity compared to the analogous triphenylbismuth diacetate reagent. It showed also a high regioselectivity as only the phenyl derivatives were detected and isolated.
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关键词
synthesis
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