Visible light-induced N-radical 5-exo/6-endo cyclization of alkenyl amides: facile access to isoindolinones/isoquinolinones

Zhen-Yao Lei,Kui Hu,Yuan-Xiang He,Shu Geng,Li-Na Chen,Shuai Zou,Li Pan, Zhi-Jun Ding,Feng Huang

Organic & Biomolecular Chemistry（2022）

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摘要

An efficient N-centered radical intramolecular cyclization reaction of alkenyl amides induced by visible light was described. In this process, an alkenyl amide underwent 5-exo/6-endo cyclization to selectively yield two critical alkaloid structures, namely isoindolinones and isoquinolinones.

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关键词

alkenyl amides,isoindolinones/isoquinolinones,cyclization,light-induced,n-radical

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