Stereoselective Synthesis of cis‐β‐Methyl‐ and Phenyl‐Substituted Alkenylboronates by Platinum‐Catalyzed Dehydrogenative Borylation

Toshimichi Ohmura,Yuta Takasaki,Hideki Furukawa,Michinori Suginome

Angewandte Chemie（2009）

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摘要

Changing places: Intramolecular B(pin)/H exchange took place in the presence of a platinum-phosphane catalyst, giving synthetically useful cis-beta-methyl-substituted alkenylboronates stereoselectively (see scheme; B(pin) = 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl).

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关键词

synthesis,platinum‐catalyzed

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