Synthesis of C-1 Alkyl and Aryl Glycals from Pyranosyl or Furanosyl Chlorides by Treatment with Organolithium Reagents.
ChemInform（2009）
Abstract
Glycosyl chlorides, with ether or isopropylidene acetal protecting groups, readily available from furanoses or pyranoses, can be conveniently transformed into C-1 alkyl or aryl glycals by reaction with alkyl or aryl organolithium reagents.
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Key words
aryl glycals,furanosyl chlorides,organolithium reagents,pyranosyl,synthesis
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