Asymmetric Synthesis of 2‐Alkyl‐3‐phosphonopropanoic Acid Derivatives via Rh‐Catalyzed Asymmetric Hydrogenation.

ChemInform(2012)

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摘要
The commercially available ferrocene-chiral diphosphine ligand FDP is highly effective for the hydrogenation of 3-arylpropenoates to give the corresponding propanoates with up to 98% e.e.
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