"One-pot" tandem C-H borylation/1,4-conjugate addition/reduction sequence.
Organic Letters(2010)
Abstract
A microwave-assisted, one-pot, iridium-catalyzed aromatic C-H borylation/rhodium-catalyzed 1,4-conjugate addition sequence provides a highly robust protocol suitable for high-throughput array synthesis. Selective formation of either β-aryl-substituted ketones or the corresponding alcohols can be achieved in good overall yields by simple variation of the reaction conditions.
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Key words
addition/reduction,addition/reduction,one-pot
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