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4,10-Diformyl-2,6,8,12-tetra­nitro-2,4,6,8,10,12-hexa­azatetra­cyclo­[5.5.0.05,9.03,11]dodeca­ne

Acta Crystallographica Section E-structure Reports Online(2010)

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摘要
The title compound TNDFIW, C8H8N10O10, is a caged heterocycle substituted with four nitro and two formyl groups. It is related to the hexa­azaisowurtzitane family of high-density high-energy polycyclic cage compounds. Four nitro groups are appended to the four N atoms of the two five-membered rings, while the other two formyl groups are attached to the two N atoms of the six-membered ring, which adopts a boat conformation. The compound has a cage structure which is constructed from one six-membered and two five-membered rings which are closed by a C—C bond, thus creating two seven-membered rings. There are a number of close intermolecular contacts [O⋯O = 2.827 (5), 2.853 (4) and 2.891 (5) A; O⋯N = 2.746 (2) and 2.895 (2) A] The calculated density of TNDFIW is 1.891 Mg m−3.
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