Readily Available Chiral Phosphine—Aminophosphine Ligands Derived from 1-Phenylethylamine for Rh-Catalyzed Enantioselective Hydrogenations.

Xiao-Mao Zhou,Jia-Di Huang,Li-Bin Luo,Cheng-Lu Zhang,Zhuo Zheng,Xiang-Ping Hu

ChemInform（2010）

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摘要

Among the novel phosphineaminophosphine derivatives prepared, effective ligands are identified for the Rh-catalyzed asymmetric hydrogenation of enamides (II), Z-β-dehydroamino acid esters (VI), and itaconate (IX).

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