Reduction of Nitriles into Aldehydes Using a TMDS/V(O)(OiPr)3 Reducing System.

Stephane Laval,Wissam Dayoub,Leyla Pehlivan,Estelle Métay,Dominique Delbrayelle,Gerard Mignani,Marc Lemaire

ChemInform（2014）

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摘要

Abstract A simple and convenient method for the chemoselective reduction of nitriles into aldehydes using a 1,1,3,3-tetramethyldisiloxane (TMDS)/triisopropoxyvanadium(V) oxide reducing system is described. Aromatic as well as aliphatic nitriles are reduced into the corresponding aldehydes in moderate to good yields.

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关键词

Hypervalent Iodine Compounds,Dehydrogenation

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