Zn‐Catalyzed Enantio‐ and Diastereoselective Formal [4 + 2] Cycloaddition Involving Two Electron‐Deficient Partners: Asymmetric Synthesis of Piperidines from 1‐Azadienes and Nitro‐Alkenes.
ChemInform(2015)
Abstract
The novel bisoxazoline diphenylamine ligand (OXA) provides high reactivity and enantioselectivity in the title process, which is proposed to proceed in a stepwise manner via Michael-type addition of the imine to the nitroalkane followed by cyclization.
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Key words
piperidines,asymmetric synthesis,cheminform abstract,zn-catalyzed,electron-deficient,nitro-alkenes
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