Zn‐Catalyzed Enantio‐ and Diastereoselective Formal [4 + 2] Cycloaddition Involving Two Electron‐Deficient Partners: Asymmetric Synthesis of Piperidines from 1‐Azadienes and Nitro‐Alkenes.

ChemInform(2015)

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Abstract
The novel bisoxazoline diphenylamine ligand (OXA) provides high reactivity and enantioselectivity in the title process, which is proposed to proceed in a stepwise manner via Michael-type addition of the imine to the nitroalkane followed by cyclization.
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Key words
piperidines,asymmetric synthesis,cheminform abstract,zn-catalyzed,electron-deficient,nitro-alkenes
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